Shell tailoring of core–shell nanoparticles for heterogeneous catalysis

Architecturally Controlled Bimetallic Nanoparticles for Heterogeneous Catalysis

Title of Dissertation/Thesis: Architecturally Controlled Bimetallic Nanoparticles for Heterogeneous Catalysis Shenghu Zhou, Doctor of Philosophy, 2007 Thesis Directed By: Professor Bryan W. Eichhorn Department of Chemistry and Biochemistry This work develops synthetic methods for architecturally controlled AuPt and CuPt bimetallic nanomaterials. The AuPt heteroaggregate, AuPt alloy spherical na...

Nanoparticles for heterogeneous catalysis: new mechanistic insights.

Metallic nanoparticles finely dispersed over oxide supports have found use as heterogeneous catalysts in many industries including chemical manufacturing, energy-related applications and environmental remediation. The compositional and structural complexity of such nanosized systems offers many degrees of freedom for tuning their catalytic properties. However, fully rational design of heterogen...

Tailoring Core-Shell Polymer-Coated Nanoparticles as Block Copolymer Surfactants

The effect of core-shell polymer-coated nanoparticles on block copolymer morphology is investigated systematically by controlling particle positioning within a block copolymer template. Our approach of varying the areal chain density (Σ) of short thiol terminated polystyrene (PS-SH) brushes on the particles where the molecular weight (Mn) of the PS ligands (2.5 kg/mol) is used to control the fr...

High-performance heterogeneous catalysis with surface-exposed stable metal nanoparticles

Protection of metal nanoparticles from agglomeration is critical for their functions and applications. The conventional method for enhancing their stability is to cover them with passivation layers to prevent direct contact. However, the presence of a protective shell blocks exposure of the metal species to reactants, thereby significantly impeding the nanoparticles' utility as catalysts. Here,...

Nanoparticles for catalysis.